Cornell universitys environmental risk analysis program has identified. Jul 01, 2014 information on methyl bromide also known as bromomethane and monobromomethane, for use in responding to chemical incidents. The acceptable air concentration level for persons exposed to methyl bromide is 5 ppm 20 mgm3. Persons whose clothing or skin is contaminated with liquid methyl bromide temperatures less than 38. The main sources of information for this fact sheet. Epa, pesticide product label, methyl bromide 100, 06242002. Methyl bromide is listed in the montreal protocol as a controlled substance with an odp ozone depleting potential of 0. Keep msds to hand as they contain vital information for emergencies. This colorless, odorless, nonflammable gas is produced both industrially and biologically. Methyl bromide also has use as an industrial chemical.
Safety data sheets and other chemical safety information are available online. Please call npic with any questions you have about pesticides at. No warranty, express or implied, is made and labchem inc. Methyl bromide transition program national institute of. The methyl bromide transition program mbt addresses the immediate needs and the costs of transition that have resulted from the phaseout of the pesticide methyl bromide. Beginning january 1, 2005, production and use of methyl bromide will stop in the united states, except for emergency and critical uses 5. Methyl bromide page 1 of 5 material safety data sheet 1. C c persons exposed only to methyl bromide gas do not pose substantial risks of secondary. If you are an industry stakeholder or other interested party that would like to be part of this process, please contact us. Since methyl bromide is a gas at ambient temperatures, the most significant route of exposure is inhalation. Our msds database is an easy to use, do it yourself tool, and best of all.
Methyl bromide is a fumigant used to control pests in agriculture and shipping. Compliance with the tolerance levels specified below is to be. Of this share, 83 percent was used for preplant soil fumigation, 11 percent for postharvest treatment of stored commodities, and 6 percent for fumigation of structures. Methyl methyl bromide bromide emergency emergency response. Methyl bromide labels table 1 summarizes the differences between existing methyl bromide mb labels and mb manufactured after october 1, 2016. However, any release of methyl bromide or methyl bromide in a mixture of methyl bromide chloropicrin that exceeds the pound rq for methyl bromide within a 24hour period must be reported to the national response center at 18004248802, and any other applicable federal, state, and local emergency agencies. Oct 21, 2014 synonyms include bromomethane, monobromomethane, isobrome, and methyl fume.
Methyl bromide is used for a nonqps application if it is used for an application that is not a qps application and other than as a feedstock. Methyl bromide is not expected to run off fields to surface water because of application methods. The chloropicrin readily causes pain and watering and closure of the eyes and will warn against presence of methyl bromide ga, e. It is a colorless, nonflammable gas with no distinct smell. It is used as a fumigant against insects and rodents in food, tobacco, and nursery stock. Bromomethane, commonly known as methyl bromide, is an organobromine compound with formula c h 3 br. Since the chemical is a gas at ordinary temperatures, it is compressed and applied as a liquid. Nptn general fact sheets are designed to answer questions. Methyl bromide reassessment hrc08002 erma hearing 17 may. Four americans are recovering after being exposed to a pesticide during a trip to the u. At the end of the workshift, wash any areas of the body that may have contacted methyl bromide, whether or not known skin contact has occurred. Table 1 mb label comparison existing mb labels instructions 2016 mb labels instructions 1. This information is not meant to replace material safety data sheets for the specific chemicals used in your experiments. Other names for bromomethane are methyl bromide, monobromomethane, and methyl fume.
Section 1 identification of the material and supplier. For more detailed information, refer to the treatment manual. The wide transboundary movement of methyl bromide and products treated with methyl bromide make it especially appropriate for regulatory analysis. When the latter was subsequently exposed to air, enough heat was produced to ignite the methyl bromide compressed air mixture above the liquid layer. Cornell ehs provides campus wide access to chemwatch, an online safety data sheet sds database consisting of over 250,000 chemwatch authored. Obtain material safety data sheets msds for all hazardous substances from the manufacturers and make available to anyone who may be exposed. In addition, the use of liquid methyl bromide may cause severe corrosion of containers and equipment made of these metals. All persons working with methyl bromide must be knowledgeable about the haznrcs, and. Cornell university has a contract with infotrac to provide the 24hour emergency response coverage for hazardous material shipments. The msds sheets are available either from the chemical manufacturer. In addition, the use of liquid methyl bromide may cause severe corrosion of containers and equipment made of. Methods and materials for containment stop leak if you can do so without risk.
Manufacturers and importers of methyl bromide need to ensure that hazardous chemicals are labelled and safety data sheets sds are prepared and provided. Data sheet sds database consisting of over 250,000 chemwatch authored. Studies in humans indicate that the lung may be severely injured by the acute shortterm inhalation of. Methyl bromide, also called bromomethane, a colourless, nonflammable, highly toxic gas readily liquefied belonging to the family of organic halogen compounds. Methyl bromide phaseout of ozonedepleting substances ods. Methyl bromide quarantine fumigant sds cardinal professional. Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. The air concentration level is measured by a direct reading detection device, such as a mathesonkitagawa, draeger, or sensidyne. Methyl bromide formulations contain chloropicrin, an irritant and lacrimator, as a warning agent. Keep cylinders cool by spraying with water until well after fire is out. Historically, the united states us has consumed the bulk of total methyl bromide annually, 42 million pounds 29. Physical properties and health effects of pesticides used on. Methyl bromide has been a pest and disease control tactic critical to pest management systems for decades for soilborne and postharvest pests.
Before using, read and follow all label precautions and directions, including the manual for safe handling of methyl bromide products no. The methyl bromide is a recognized ozonedepleting chemical. Methyl bromide is not spontaneously combustible, but it poses a hazard when exposed to sparks or flame. Persons exposed only to methyl bromide gas do not pose substantial risks of secondary contamination.
Studies in humans indicate that the lung may be severely injured by the acute shortterm inhalation of methyl bromide. Fumigation handlers entering the fumigation site before methyl bromide has been introduced to the treatment. John when they were exposed to a chemical believed to be methyl bromide which had been used as a pest control fumigant. Methyl bromide mebr is a broad spectrum agricultural pesticide that has been. Methyl bromide in a steel tank reacted with an aluminum tube part of the level gauge producing methyl aluminum bromide. Epa has classified methyl bromide as a group d, not classifiable as to human carcinogenicity. This regulation establishes a tolerance for residues of methyl bromide in or on cotton, undelinted seed under the federal food, drug, and cosmetic act ffdca because there is a need for imported undelinted cottonseed for use as additional feed for dairy cattle in the united states. Do not eat, smoke, or drink where methyl bromide is handled, processed, or stored, since the chemical can be. Timelimited tolerances as listed in the following table are established for residues of the fumigant methyl bromide, including its metabolites and degradates, in or on the specified agricultural commodities, resulting from use of the pesticide pursuant to fifra section 18 emergency exemptions. When fighting fires involving methyl bromide, wear safety boots, nonflammable overalls, gloves, hat, goggles and selfcontained breathing apparatus. Hazards identification this material is considered to be hazardous according to regulat ory guidelines see msds section 15.
The department of the environment is closely monitoring international trends in relation to the control of quarantine and preshipment use of methyl bromide. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Possible misuse of methyl bromide poisons family of four. Physiological and biochemical behavioral characteristics na environmental characteristics hydrolysis data indicate that methyl bromide breaks down at a rate of 1. The user must determine suitability of this information for his application. Methyl bromide ga is a colourless poisonous liquid gas containing 2 % chloropicrin teargas as a warning agent. However, any release of methyl bromide or methyl bromide in a mixture of methyl bromidechloropicrin that exceeds the pound rq for methyl bromide within a 24hour period must be reported to the national response center at 18004248802, and any other applicable federal, state, and local emergency agencies. First aid measures as this product is a gas, refer to the inhalation section. It has a tetrahedral shape and it is a recognized ozonedepleting chemical. Information on methyl bromide also known as bromomethane and monobromomethane, for use in responding to chemical incidents.
Aeration and reentry after fumigation, treated areas must be aerated until the level of methyl bromide is 5 ppm or less. List, and are only permitted to use methyl bromide for the purpose for which the exemption was granted. On skin contact with methyl bromide, immediately wash or shower to remove the chemical. The family a husband and wife, and their two teenage sons were renting a villa at a resort in st. Follow the instructions on the label or permit for storage, use and disposal. Methyl bromide chemical fact sheet 886 cornell university. Therefore, along with other countries, the united states has phased out production and consumption of methyl bromide with important exceptions for critical uses as well as quarantine and preshipment. Sodium bromide 6 information in this msds is from available published sources and is believed to be accurate. The methyl bromide is an organic compound with the formula ch 3 br. However, the use of liquid methyl bromide with aluminum, magnesium, zinc and alkali metals may result in the liberation of toxic gases, and possible fire and explosion. Methyl bromide mebr is an odorless, colorless gas that is used primarily as a soil fumigant and commodity fumigant to control pests across a wide range of agricultural sectors. Methyl ethyl ketone 78 93 3 100% all concentrations are percent by weight unless material is a g as.
Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Methyl bromide is a colorless gas or volatile liquid which is usually odorless, but has a sweet, chloroformlike odor at high concentrations. In a field study conducted in 1990, following this method for sampling and analysis, they found that the methyl bromide had a capacity problem and poor storage ref. Methyl bromide is a broadspectrum pesticide primarily used for soil fumigation, commodityquarantine treatment, and structural fumigation. When the latter was subsequently exposed to air, enough heat was produced to ignite the methyl bromidecompressed air mixture above the liquid layer. Besides, it is colourless gas with a chloroformlike odour. Dec 14, 2011 historically, the united states us has consumed the bulk of total methyl bromide annually, 42 million pounds 29. It also occurs naturally in small amounts in the ocean where it is formed, probably by algae and kelp. See the user safety requirements section for additional restrictions. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Methyl bromide bromomethane 74839 hazard summary methyl bromide is used as a fumigant and pesticide.
Methyl bromide is a highly hazardous material and should be used only by individuals trained in its proper use. Methyl bromide department of agriculture, water and the. At the same time, methyl bromide is manufactured and used in other countries, and some other nations require food from the u. If the pesticide product enduse labeling contains hazard. Methyl bromide 74839 yes yes yes yes yes yes the following statements are provided under the california safe drinking water and toxic enforcement. Approved cues mustbe current in the year of methyl bromide use.
Synonyms include bromomethane, monobromomethane, isobrome, and methyl fume. With the cas registry number 74839, it is also named as dlmethylbromide. Chemical data sheets of niosh, ntp, ipcs, cornell university, great lakes chemical corp. Chemwatch sds library cornell ehs cornell university.
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